Analyzing Cinnamon Spice Adulteration with Spectroscopy: The Influence of Data Preprocessing on Multivariate Prediction Models

Masoudi, Mohammad; Khodabakhshian, Rasool; Golzarian, Mahmood Reza

doi:10.22104/ift.2025.7722.2223

Analyzing Cinnamon Spice Adulteration with Spectroscopy: The Influence of Data Preprocessing on Multivariate Prediction Models

Document Type : Research Article

Authors

¹ Department of Biosystem Engineering, Ferdowsi University of Mashhad

² Assistant Professor Department of Biosystems Engineering Ferdowsi University of Mashhad

³ School of Computer Science and Information Technology, Murdoch University, Perth, Australia

10.22104/ift.2025.7722.2223

Abstract

Detecting fraud in the cinnamon supply chain is critical for ensuring consumer safety and maintaining product integrity. Recent advances in spectral data preprocessing techniques offer enhanced accuracy in identifying adulterants in spices like cinnamon. This study investigates the impact of different spectral preprocessing techniques on predicting adulterants—specifically soybean powder, hazelnut shell powder, and dry bread powder—mixed with cinnamon powder using spectroscopy combined with multivariate analysis. The transmittance spectra were collected across the mid-infrared range of 400–4000 cm⁻¹, and Partial Least Squares Regression (PLSR) was employed to model the adulteration levels based on these spectra. Various preprocessing methods were applied to optimize the spectral data. Among them, orthogonal signal correction (OSC) combined with detrending yielded the highest predictive accuracy, with a coefficient of prediction (R²p) ranging from 0.900 to 0.981. Conversely, Extended Multiplicative Scatter Correction (EMSC) and Savitzky-Golay second derivative (D2) were less effective, with R²p values between 0.115 and 0.931. Soybean powder was the easiest adulterant to detect, with a prediction error range of 5–10%. These findings underscore the importance of selecting appropriate preprocessing techniques to improve the accuracy of fraud detection in cinnamon powder using spectroscopic methods.

Graphical Abstract

Highlights

The effect of different preprocessing methods on FTIR spectra was investigated.
PLSR prediction accuracy was evaluated using different preprocessing methods.
Preprocessing methods can improve or hinder the performance of PLSR model.
A methodological approach to preprocessing FTIR spectra of cinnamon spice is proposed.

Keywords

Main Subjects

Food biotechnology

References

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